MALLINCKRODT BAKER INC -- POTASSIUM IODIDE, 1127 -- -
===================== Product Identification ===================== Product ID:POTASSIUM IODIDE, 1127 MSDS Date:12/08/1996 FSC:NIIN:Submitter:N EN Status Code:A === Responsible Party === Company Name:MALLINCKRODT BAKER INC Address:222 RED SCHOOL LANE City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Info Phone Num:800-582-2537 Emergency Phone Num:908-859-2151 Resp. Party Other MSDS Num.:P5906 Chemtrec Ind/Phone:(800)424-9300 CAGE:70829 === Contractor Identification === Company Name:MALLINCKRODT BAKER, INC. Address:222 RED SCHOOL LANE Box:City:PHILLIPSBURG State:NJ ZIP:08865 Country:US Phone:800-582-2537 CAGE:70829 ============= Composition/Information on Ingredients ============= Ingred Name:POTASSIUM IODIDE (HAZARDOUS) CAS:7681-11-0 RTECS #:TT2975000 Minumum % Wt:90. Maxumum % Wt:100. Other REC Limits:N/K OSHA PEL:15 MG/M3 OSHA STEL:N/K ACGIH TLV:10 MG/M3 ACGIH STEL:N/K ===================== Hazards Identification ===================== Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE: INHALATION: MAY CAUSE IRRITATION TO THE RESPIRATORY TRACT. SYMPTOMS MAY INCLUDE COUGHING AND SHORTNESS OF BREATH. INGESTION: LARGE ORAL DOSES MAY CAUSE IRRITATION TO THE GASTROINTESTINAL TRACT. SKIN: MAY CAUSE IRRITATION WITH REDNESSAND PAIN. EYES: MAY CAUSE IRRITATION, REDNESS AND PAIN. CHRONIC: CHRONIC INGESTION OF IODIDES MAY PRODUCE "IODISM", WHICH MAY BE MANIFESTED BY SKIN RASH, RUNNIN G NOSE, HEADACHE AND IRRITATION OF MUCOUS MEMBRANES. WEAKNESS, ANEMIA, LOSS OF WEIGHT, AND GENERAL DEPRESSION MAY ALSO OCCUR. Explanation of Carcinogenicity:POTASSIUM IODIDE (CAS # 7681-11-0): NOT LISTED. Effects of Overexposure:SEE HEALTH HAZARDS. Medical Cond Aggravated by Exposure:NO INFORMATION FOUND. ======================= First Aid Measures ======================= First Aid:INHALATION: REMOVE TO FRESH AIR. GET MEDICAL ATTENTION FOR ANY BREATHING DIFFICULTY. INGESTION: INDUCE VOMITING IMMEDIATELY AS DIRECTED BY MEDICAL PERSONNEL. NEVER GIVE ANYTHING BY MOUTH TO AN UNCONSC IOUS PERSON. SKIN: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHING AND SHOES. WASH CLOTHING BEFORE REUSE. THOROUGHLY CLEAN SHOES BEFORE REUSE. GET MEDICAL ATTENTION IF IRRITATION DEVELOPS. EYES: IMMEDIATELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES, LIFTING UPPER AND LOWER EYELIDS OCCASIONALLY. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. ===================== Fire Fighting Measures ===================== Extinguishing Media:USE ANY MEANS SUITABLE FOR EXTINGUISHING SURROUNDING FIRE. Fire Fighting Procedures:WEAR NIOSH APPROVED SCBA AND FULL PROTECTIVE EQUIPMENT . Unusual Fire/Explosion Hazard:NOT CONSIDERED TO BE A FIRE OR EXPLOSION HAZARD. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF LEAK OR SPILL. WEAR APPROPRIATE PERSONAL PROTECTIVE EQUIPMENT AS SPECIFIED IN CONTROL MEASURES SECTION. SWEEP UP AND CONTAINERIZE FOR RECLAMATION OR DISPOSAL. VACUUMING OR WET-SWEEPI NG MAY BE USED TO AVOID DUST DISPERSAL. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP IN A TIGHTLY CLOSED LIGHT-RESISTANT CONTAINER, STORED IN A COOL, DRY, VENTILATED AREA. PROTECT AGAINST PHYSICAL DAMAGE. ISOLATE FROM INCOMPATIBLE SUBSTANCES. PROLONGED STORAGE IS NOT RECOMMENDED BECAUSE OF POSSIBLE DEGRADATION PROBLEMS, INCLUDING YELLOWING OF THE POTASSIUM IODIDE PRODUCT. Other Precautions:ALWAYS INSPECT THE POTASSIUM IODIDE'S COLOR AND OVERALL QUALITY BEFORE USE. CONTAINERS OF THIS MATERIAL MAY BE HAZARDOUS WHEN EMPTY SINCE THEY RETAIN PRODUCT RESIDUES (DUST, SOLIDS); OBSERVE ALL WARNI NGS AND PRECAUTIONS LISTED FOR THE PRODUCT. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:IF EXPOS LIM IS EXCEEDED, A NIOSH APPRVD HALF-FACE DUST/MIST RESP MAY BE WORN FOR UP TO 10 TIMES EXPOS LIM/MAX USE CONC SPECIFIED BY APPROP REGULATORY AGENCY/RESP SUPPLIER, WHICHEVER IS LOWEST. A NIOS H APPRVD FULL-FACE PIECE DUST/MIST RESP MAY BE WORN UP TO 50 TIMES EXPOS LIM/MAX USE CONC SPECIFIED BY APPROP REGULATORY AGENCY/RESP SUPPLIER, (SUP DAT) Ventilation:A SYS OF LOC &/OR GEN EXHST IS REC TO KEEP EMPLOYEES EXPOS BELOW AIRBORNE EXPOS LIMS. LOC EXHST VENT IS GEN PREF BECAUSE IT CAN CTL EMISSIONS OF (OTHER INFO) Protective Gloves:WEAR IMPERVIOUS GLOVES . Eye Protection:ANSI APPROVED CHEMICAL WORKERS GOGGLES . Other Protective Equipment:ANSI APPROVED EMERGENCY EYEWASH AND DELUGE SHOWER . LAB COAT, APRON OR COVERALLS. Work Hygienic Practices:AVOID CONTACT WITH EYES, SKIN AND CLOTHING. AVOID BREATHING DUST. KEEP CONTAINER CLOSED. USE WITH ADEQUATE VENTILATION. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health RESP PROT: WHICHEVER IS LOWEST. FOR EMERS/INSTANCES WHERE EXPOS LEVELS ARE NOT KNOWN, USE A NIOSH APPRVD FULL-FACEPIECE POS-PRESS, AIR-SUPPLIED RESP. WARNING: AIR-PURIFYING RESPS DO NOT PROTECT WORKER S IN OXYGEN-DEFICIENT ATMOSPHERES. PHYSICAL DATA: DENSITY: 3.1. ================== Physical/Chemical Properties ================== Boiling Pt:=1330.C, 2426.F Melt/Freeze Pt:=680.C, ######F Vapor Pres:1 @ 745C (1373F) pH:7-9 Solubility in Water:140 GRAMS/100 GM IN WATER Appearance and Odor:WHITE CRYSTALS; ODORLESS. Percent Volatiles by Volume:0 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES DIAZONIUM SALTS; DIISOPROPYL PEROXYDICARBONATE, OXIDANTS, BROMINE AND CHLORINE TRIFLUORIDES, FLUORINE PERCHLORATE, CALOMEL (MERCUROUS CHLORIDE), POTASSIUM CHLORATE, METALLIC SALTS, TARTARIC AND OTHER ACIDS. Stability Condition to Avoid:ON LONG EXPOSURE TO AIR BECOMES YELLOW DUE TO RELEASE OF IODINE. AVOID AIR, MOISTURE, LIGHT AND INCOMPATIBLES. Hazardous Decomposition Products:OXIDES OF THE CONTAINED METAL AND HALOGEN, POSSIBLY ALSO FREE, OR IONIC HALOGEN. =================== Toxicological Information =================== Toxicological Information:INVESTIGATED AS A MUTAGEN, REPRODUCTIVE EFFECTOR. ===================== Ecological Information ===================== Ecological:ENVIRONMENTAL FATE: NO INFORMATION FOUND. ENVIRONMENTAL TOXICITY: NO INFORMATION FOUND. ==================== Disposal Considerations ==================== Waste Disposal Methods:WHATEVER CANNOT BE SAVED FOR RECOVERY/RECYCLING SHOULD BE MANAGED IN APPROPRIATE & APPROVED WASTE DISPOSAL FACILITY. PROCESSING, USE/CONTAMINATION OF PRODUCT MAY CHANGE WASTE MANAGEMENT OPTIONS. STATE & LOCAL DISP REGULATIONS MAY DIFFER FROM FEDERAL DISP REGULATIONS. DISPOSE OF CONTAINER & UNUSED CO NTENTS I/A/W FEDERAL, STATE & LOCAL REQUIREMENTS. =================== MSDS Transport Information =================== Transport Information:NOT REGULATED. ===================== Regulatory Information ===================== SARA Title III Information:POTASSIUM IODIDE (CAS # 7681-11-0): NOT LISTED IN SARA SECTION 302 RQ, SECTION 302 TPQ, SECTION 313 LIST, SECTION 313 CHEMICAL CATEGORIES. SARA 311/312: ACUTE: YES; CHRONIC: YES; FIRE: NO; PRESSURE: N O; REACTIVITY: NO (PURE/SOLID). Federal Regulatory Information:POTASSIUM IODIDE (CAS # 7681-11-0): LISTED IN TSCA, EC, JAPAN, AUSTRALIA, KOREA, CANADA DSL, PHILLIPINES; NOT LISTED IN CANADA NDSL, CERCLA, RCRA 261.33, TSCA 8 (D). CHEMICAL WEAPONS CONVENTION: NO. T SCA 12 (B): NO. CDTA: NO. AUSTRALIAN HAZCHEM CODE: NO INFORMATION FOUND. POISON SCHEDULE: NO INFORMATION FOUND. WHMIS: THIS MSDS HAS BEEN PREPARED ACCORDING TO THE HAZARD CRITERIA OF THE CONTROLLED PR ODUCTS REGULATIONS (CPR) AND THE MSDS CONTAINS ALL OF THE INFORMATION REQUIRED BY THE CPR. State Regulatory Information: ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.