CAROLINA BIOLOGICAL SUPPLY CO -- SAFRANIN COUNTER STAIN FOR GRAM METHOD, 15-4724A -- 6810-00000000000
===================== Product Identification ===================== Product ID:SAFRANIN COUNTER STAIN FOR GRAM METHOD, 15-4724A MSDS Date:01/02/1998 FSC:6810 NIIN:00000000000 Status Code:A === Responsible Party === Company Name:CAROLINA BIOLOGICAL SUPPLY CO Address:2700 YORK RD City:BURLINGTON State:NC ZIP:27215-3387 Country:US Info Phone Num:800-227-1150 Emergency Phone Num:800-227-1150 Chemtrec Ind/Phone:(800)424-9300 CAGE:59896 === Contractor Identification === Company Name:CAROLINA BIOLOGICAL SUPPLY CO Address:2700 YORK RD Box:City:BURLINGTON State:NC ZIP:27215-3387 Country:US Phone:800-227-1150/910-584-0381 Contract Num:MDA414-98-01180122 CAGE:59896 ============= Composition/Information on Ingredients ============= Ingred Name:SAFRANIN CAS:477-73-6 RTECS #:SG1623000 = Wt:.25 Other REC Limits:NONE RECOMMENDED Ingred Name:ETHYL ALCOHOL CAS:64-17-5 RTECS #:KQ6300000 = Wt:9.5 Other REC Limits:NONE RECOMMENDED OSHA PEL:1000 PPM ACGIH TLV:50 PPM Ingred Name:METHYL ISOBUTYL KETONE (DENATURANT) CAS:108-10-1 RTECS #:SA9275000 = Wt:.38 OSHA PEL:50 PPM OSHA STEL:75 PPM ACGIH TLV:50 PPM ACGIH STEL:75 PPM EPA Rpt Qty:5000 LBS DOT Rpt Qty:5000 LBS Ingred Name:HEXANE (DENATURANT) CAS:110-54-3 RTECS #:MN9275000 = Wt:.12 OSHA PEL:500 PPM ACGIH TLV:50 PPM EPA Rpt Qty:1 LB DOT Rpt Qty:1 LB ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT): 7,060 MG/KG (ETHANOL) Routes of Entry: Inhalation:YES Skin:NO Ingestion:NO Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:TARGET ORGANS: EYES, SKIN, NOSE. ACUTE: EYES: MAY CAUSE IRRITATION. SKIN: MAY CAUSE IRRITATION. INHALATION: MAY CAUSE IRRITATION TO RESPIRATORY TRACT. INGESTION: MAY CAUSE GASTROINTESTINAL DISCOMFORT. Explanation of Carcinogenicity:EACH OF THE FOUR INGREDIENTS ARE NOT LISTED AS CAUSING CANCER BY IARC, NTP, OSHA. Effects of Overexposure:MAY CAUSE IRRITATION TO EYES, SKIN, AND MUCOUS MEMBRANES UNDER PROLONGED EXPOSURE. IF SWALLOWED, MAY CAUSE GASTROINTESTINAL IRRITATION, NAUSEA, VOMITING, DIARRHEA. Medical Cond Aggravated by Exposure:PERSONS WITH PRE-EXISTING CONDITIONS OF THE EYES, SKIN, AND NOSE MAY BE MORE SUSCEPTIBLE TO THE EFFECTS OF THIS PRODUCT. TARGET ORGANS: EYES, SKIN, NOSE. ======================= First Aid Measures ======================= First Aid:EYES: FLUSH WITH WATER FOR AT LEAST 15 MINUTES, RAISING AND LOWERING EYELIDS. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. SKIN: WASH EXPOSED AREA FOR AT LEAST 15 MINUTES. REMOVE CONTAMINATED CLOTHIN G AND LAUNDER BEFORE REUSE. GET MEDICAL ATTENTION IF IRRITATION PERSISTS. INHALATION: MOVE TO FRESH AIR. GIVE OXYGEN IF BREATHING IS DIFFICULT. GIVE ARTIFICIAL RESPIRATION IF BREATHING HAS STOPPED. GE T MEDICAL ATTENTION. INGESTION: DO NOT INDUCE VOMITING. IF SWALLOWED, IF CONSCIOUS, GIVE PLENTY OF WATER IMMEDIATELY AND CALL A PHYSICIAN OR POISON CONTROL CENTER. NEVER GIVE ANYTHING BY MOUTH TO AN U NCONSCIOUS PERSON. ===================== Fire Fighting Measures ===================== Flash Point Method:CC Flash Point:=13.1C, 55.6F ETHYL ALCOHOL Autoignition Temp:=422.8C, 793.F Autoignition Temp Text:E. ALC Lower Limits:3.3 ETHANOL Upper Limits:19 ETHANOL Extinguishing Media:USE MEDIA SUITABLE TO EXTINGUISH SURROUNDING FIRE. Fire Fighting Procedures:FIREFIGHTERS SHOULD WEAR FULL PROTECTIVE EQUIPMENT AND NIOSH APPROVED SELF-CONTAINED BREATHING APPARATUS. Unusual Fire/Explosion Hazard:FLAMMABLE VAPORS MAY BE PRESENT, IF PRODUCT IS HEATED, WHICH MAY IGNITE IF EXPOSED TO HEAT, SPARKS, AND OPEN FLAME. MFRS MSDS SHOWS NFPA RATING FOR PRODUCT AS "FIRE 2". RATING IS FOR LIQUID MATERIAL WITH A FLASH POINT ABOVE 100 F, BUT NOT EXCEEDING 200F. HCC FOR 100F F. P. TO 141F IS F4; FROM 141F TO 200F, HCC IS V4. ================== Accidental Release Measures ================== Spill Release Procedures:VENTILATE AREA OF SPILL. ELIMINATE ALL SOURCES OF IGNITION. REMOVE ALL NON-ESSENTIAL PERSONNEL FROM AREA. CLEAN-UP PERSONNEL SHOULD WEAR PROPER PROTECTIVE EQUIPMENT AND CLOTHING. ABSORB MATERIAL WITH SUITABLE ABSORBANT AND CONTAINERIZE FOR DISPOSAL. ====================== Handling and Storage ====================== Handling and Storage Precautions:THIS MATERIAL SHOULD BE KEPT IN AN AREA SUITABLE FOR THE STORAGE OF FLAMMABLE LIQUIDS. BOND AND GROUND CONTAINERS WHEN TRANSFERRING LIQUID. Other Precautions:AVOID BREATHING VAPORS. AVOID EYE OR SKIN CONTACT. WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING OR DRINKING. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH/MSHA CHEMICAL CARTRIDGE RESPIRATOR SHOULD BE WORN IF PEL OR TLV IS EXCEEDED. Ventilation:MECHANICAL (GENERAL) AND/OR LOCAL EXHAUST. Protective Gloves:RUBBER, NEOPRENE, PVC, OR EQUIVALENT. Eye Protection:SPLASH PROOF CHEMICAL SAFETY GOGGLES SHOULD BE WORN AT ALL TIMES. Other Protective Equipment:LAB COAT, EYE WASH STATION, AND SAFETY SHOWER. Work Hygienic Practices:OBSERVE GOOD PERSONAL HYGIENE PRACTICES AND RECOMMENDED PROCEDURES. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:F4 Spec Gravity:<1 Solubility in Water:COMPLETE Appearance and Odor:RED LIQUID WITH SLIGHT CHARACTERISTIC ODOR OF ALCOHOL. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES STRONG OXIDIZING AGENTS, WATER REACTIVE MATERIALS. Stability Condition to Avoid:HEAT, SPARKS, FLAME AND OTHER SOURCES OF IGNITION. Hazardous Decomposition Products:CARBON MONOXIDE, CARBON DIOXIDE. Conditions to Avoid Polymerization:WILL NOT OCCUR. =================== Toxicological Information =================== Toxicological Information:ETHYL ALCOHOL: LD50(ORAL RAT)= 7,060 MG/KG; LC50(IHL RAT)= 20,000 PPM/10H. METHYL ISOBUTYL KETONE: LD50 (ORAL RAT)=5,080 MG/KG; LC50 (IHL-RAT)=8,000 PPM/4H. HEXANE: LD50 (ORAL RAT)=28,710 MG/KG; TCLO (IHL HUMAN)=5,000 PPM/10M. SAFRANNIN: NONE. EFFECTS OF OVEREXPOSURE: CHRONIC: SAFRANIN: MUTATION DATA CITED. ETHYL ALCOHOL: MUTATION DATA CITED. REPRODUCTION EFFECTS DTA CITED. TUMORIGENIC DATA CITED . METHYL ISOBUTYL KEYTONE: NO CHRONIC EFFECTS DATA FOUND. HEXANE: MUTATION DATA CITED. REPRODUCTIVE EFFECTS DATA CITED. EACOF THE 4 INGREDIENTS IS NOT LISTED AS CAUSING CANCER BY IARC, NTP, OR OSHA. ===================== Ecological Information ===================== Ecological:EPA TSCA WASTE NUMBERS: NONE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE OF IN ACCORDANCE WITH LOCAL, STATE, AND FEDERAL REGULATIONS. ALWAYS CONTACT A PERMITTED WASTE DISPOSER (TSD) TO ASSURE COMPLIANCE. =================== MSDS Transport Information =================== Transport Information:NON-REGULATED. ===================== Regulatory Information ===================== SARA Title III Information:HAZARD CATEGORY FOR SARA SECTION 311/312 REPORTING: ACUTE. SAFRANIN, ETHYL ALCOHOL, HEXANE: SARA EHS SEC. 302 TPQ-NO;SARASEC. 313 CHEMICALS, NAME LIST- NO, CHEMICAL CATEGORY-NO. CERCLA SEC/ 103 RQ, LB S-NO. RCRA SEC. 261.33-NO. METHYL ISOBUTYL: ALL ABOVE CTEGORIES -NO EXCEPT CERCLA SEC.103 -RQ=5000 LBS AND RCA SEC. 261.33 -YES. Federal Regulatory Information:EPA TSCA STATUS: ON TSCA INVENTORY. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.