FREY SCIENTIFIC -- SULFURIC ACID, CONCENTRATE (SEE SUPPLEMENTAL) -- -
===================== Product Identification ===================== Product ID:SULFURIC ACID, CONCENTRATE (SEE SUPPLEMENTAL) MSDS Date:02/19/1997 FSC:NIIN:Submitter:D DG Status Code:A === Responsible Party === Company Name:FREY SCIENTIFIC Address:100 PARAGON PARKWAY City:MANSFIELD State:OH ZIP:44903 Country:US Info Phone Num:1-419-589-1900 Emergency Phone Num:(800)424-9300 Resp. Party Other MSDS Num.:XS 1120 Preparer's Name:MICHAEL RASZEJA Chemtrec Ind/Phone:(800)424-9300 CAGE:TO572 === Contractor Identification === Company Name:FREY SCIENTIFIC Address:100 PARAGON PARKWAY Box:City:MANSFIELD State:OH ZIP:44905 Country:US Phone:419-589-1900 CAGE:6U218 Company Name:FREY SCIENTIFIC Address:100 PARAGON PARKWAY Box:City:MANSFIELD State:OH ZIP:44903 Country:US Phone:1-419-589-1900 CAGE:TO572 Company Name:SCHOOL SPECIALTY INC DBA SCHOOL SPECIALTY SUPPLY Address:3525 S 9TH ST Box:1547 City:SALINA State:KS ZIP:67401-7883 Country:US Phone:913-827-0451 Contract Num:MDA414-00-T-0613 CAGE:4A560 ============= Composition/Information on Ingredients ============= Ingred Name:SULFURIC ACID CAS:7664-93-9 RTECS #:WS5600000 Minumum % Wt:80. Maxumum % Wt:100. OSHA PEL:1 MG/M3 ACGIH TLV:1 MG/M3 ACGIH STEL:3 MG/M3 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:WATER CAS:7732-18-5 RTECS #:ZC0110000 Fraction by Wt: BALANCE ===================== Hazards Identification ===================== LD50 LC50 Mixture:NO DATA PROVIDED BY RESPONSIBLE PARTY. Health Hazards Acute and Chronic:INGESTION OF SULFURIC ACID CAN CAUSE MUCOUS MEMBRANE BURNS, ABDOMINAL PAIN, RESPIRATORY DISTRESS, SHOCK, RENAL FAILURE & LESIONS OR PERFORATIONS OF ESOPHAGUS & GI TRACT. CONCENTRATED LIQUID MAY CAUSE SEVERE SKIN BURNS. REPEATED CONTACT WITH DILUTED SOLUTIONS MAY CAUSE SKIN IRRITATION & DERMATITIS. SEVERE AND/OR PERMANENT EYE DAMAGE MAY OCCUR. INHALATION OF LOW CONCENTRATIONS OF VAPORS/MISTS CAN CA USE IRRITATION OF RESPIRATORY TRACT. OVEREXPOSURE TO HIGHER CONCENTRATIONS CAUSE BRONCHIOCONSTRICTION AND LARYNGEAL SPASM OR LARYNGEAL EDEMA. Explanation of Carcinogenicity:NO DATA PROVIDED BY RESPONSIBLE PARTY. Effects of Overexposure:INGESTION OF SULFURIC ACID CAN CAUSE MUCOUS MEMBRANE BURNS, ABDOMINAL PAIN, RESPIRATORY DISTRESS, SHOCK, RENAL FAILURE & LESIONS OR PERFORATIONS OF ESOPHAGUS & GI TRACT. CONCENTRATED LIQUID MAY CAUSE SEVERE SKIN BURNS. REPEATED CONTACT WITH DILUTED SOLUTIONS MAY CAUSE SKIN IRRITATION & DERMATITIS. SEVERE AND/OR PERMANENT EYE DAMAGE MAY OCCUR. INHALATION OF LOW CONCENTRATIONS OF VAPORS/MISTS CAN CA USE IRRITATION OF RESPIRATORY TRACT. OVEREXPOSURE TO HIGHER CONCENTRATIONS CAUSE BRONCHIOCONSTRICTION AND LARYNGEAL SPASM OR LARYNGEAL EDEMA. Medical Cond Aggravated by Exposure:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================= First Aid Measures ======================= First Aid:SKIN: FLUSH WITH WATER FOR 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING. INGESTION: DO NOT INDUCE VOMITING! IF CONSCIOUS, DRINK LARGE QUANTITIES OF MILK OR WATER. GET IMMEDIATE MEDICAL ATTENTION. N EVER GIVE ANYTHING BY MOUTH TO AN UNCONSCIOUS PERSON. EYES: FLUSH WITH WATER FOR 15 MINUTES, LIFTING EYELIDS. GET IMMEDIATE MEDICAL ATTENTION. INHALATION: REMOVE TO FRESH AIR. IF NOT BREATHING. GIVE A RTIFICIAL RESPIRATION. IF BREATHING DIFFICULT, GIVE OXYGEN. GET MEDICAL ATTENTION. ===================== Fire Fighting Measures ===================== Flash Point:NON-FLAMAMBLE Extinguishing Media:DRY CHEMICALS. Fire Fighting Procedures:WEAR SELF-CONTAINED, POSITIVE-PRESSURE BREATHING APPARATUS AND FULL FIREFIGHTING PROTECTIVE CLOTHING. FIRES INVOLVING A SMALL AMOUNT OF COMBUSTIBLES MAY BE SMOTHERED BY DRY CHEMICALS. USE WATER ON COM BUSTIBLES BURNIONG IN VICINITY OF ACID BUT USE CARE AS WATER APPLIED TO ACID MAY CAUSE BOILING AND SPLATTERING. Unusual Fire/Explosion Hazard:SULFURIC ACID WILL NOT BURN BUT IS CAPABLE OF IGNITING FINELY DDIVIDED COMBUSTIBLE MATERIALS ON CONTACT. MAY REACT VIOLENTLY WITH ORGANIC MATERIALS AND WATER WITH EVOLUTION OF HEAT. ================== Accidental Release Measures ================== Spill Release Procedures:WEAR PROTECTIVE SAFETY EQUIPMENT AND CLOTHING. DILUTE SPILL CAUTIOUSLY WITH 5-6 VOLUMES OF WATER, NEUTRALIZE GRADUALLY WITH SODA ASH OR LIME. DO NOT ALLOW UNNEUTRALIZED ACID TO GET INTO SEWERS CONTAIN ING SULFIDES BECIAUSE OF DANGER OF EVOLVING HYDROGEN SULFIDE GAS. Neutralizing Agent:SODA ASH OR LIME. ====================== Handling and Storage ====================== Handling and Storage Precautions:STORE IN A COOL PLACE. WASH THOROUGHLY AFTER HANDLING. KEEP CONTAINER TIGHTLY CLOSED WHEN NOT IN USE. Other Precautions:READ LABEL ON CONTAINER BEFORE USING. DO NOT WEAR CONTACT LENSES WHEN WORKING WITH CHEMICALS. AVOID CONTACT WITH SKIN, EYES, MUCOUS MEMBRANES AND CLOTHING. REMOVE AND WASH CONTAMINATED CLOTHING. FOR L ABORATORY USE ONLY. NOT FOR DRUG, FOOD OR HOUSEHOLD USE. KEEP OUT OF REACH OF CHILDREN. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:WEAR A NIOS/MSHA-APPROVED RESPIRATOR SUITABLE FOR LEVEL OF EXPOSURE. Ventilation:LOCAL EXHAUST: RECOMMENDED. MECHANICAL (GENERAL): RECOMMENDED. SPECIAL/OTHER: NO. Protective Gloves:RUBBER. Eye Protection:CHEMICAL SAFETY GLASSES. Other Protective Equipment:GOGGLES, FACESHIELD, SMOCK, APRON, EYE WASH STATION, PROPER GLOVES. Work Hygienic Practices:REMOVE AND WASH CONTAMINATED CLOTHING AND SHOES. WASH THOROUGHLY AFTER HANDLING. Supplemental Safety and Health SCHOOL SPECIALTY PART NUMBER: 79210. ================== Physical/Chemical Properties ================== HCC:C1 Vapor Pres:VARIABLE Spec Gravity:1.4 Solubility in Water:COMPLETE Appearance and Odor:CLEAR TO SLIGHTLY CLOUDY OILY LIQUID; ODORLESS TO SLIGHTLY PUNGENT ODOR. Percent Volatiles by Volume:0-20: WEIGHT ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES WATER, MANY METALS AND STRONG ALKALI MATERIALS. CONTACT WITH OXIDIZERS MAY CAUSE VIOLENT REACTION/EXPLOSION, OR FORM UNSTABLE COMPOUNDS. CONTACT WITH ORGANIC MATERIALS MAY CAUSE IN HIGHLY EXOTHERMIC REACTIONS. Stability Condition to Avoid:EXCESSIVE TEMPERATURE AND HEAT. Hazardous Decomposition Products:THERMAL DECOMPOSITION OR COMBUSTION MAY PRODUCE SULFUR TRIOXIDE AND/OR SULFUR DIOXIDE. TOXIC AND EXPLOSIVE HYDROGEN SULFIDE MAY BE FORMED. =================== Toxicological Information =================== Toxicological Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. ===================== Ecological Information ===================== Ecological:NO DATA PROVIDED BY RESPONSIBLE PARTY. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO FEDERAL STATE OR LOCAL LAWS. THESE DISPOSAL GUIDELINES ARE INTENDED FOR THE DISPOSAL OF CATALOG-SIZE QUANTITIES ONLY. DISPOSE OF IN ACCORDANCE WITH F EDERAL, STATE AND LOCAL REGULATIONS. =================== MSDS Transport Information =================== Transport Information:US DOT: SULFURIC ACID, 8, UN1830, PGII. ===================== Regulatory Information ===================== SARA Title III Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. Federal Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. State Regulatory Information:NO DATA PROVIDED BY RESPONSIBLE PARTY. ======================= Other Information ======================= Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.