ABSOLUTE STANDARDS INC -- METHYLENE CHLORIDE, 9315 -- 6810-00N038593
===================== Product Identification ===================== Product ID:METHYLENE CHLORIDE, 9315 MSDS Date:11/02/1992 FSC:6810 NIIN:00N038593 === Responsible Party === Company Name:ABSOLUTE STANDARDS INC Address:498 RUSSELL ST City:NEW HAVEN State:CT ZIP:06513 Country:US Info Phone Num:800-368-1131 Emergency Phone Num:800-368-1131 CAGE:0TZV1 === Contractor Identification === Company Name:ABSOLUTE STANDARDS INC Address:44 ROSSOTTO DR Box:5585 City:HAMDEN State:CT ZIP:06518 Country:US Phone:203-281-2917 CAGE:0TZV1 ============= Composition/Information on Ingredients ============= Ingred Name:METHANE, DICHLORO-; (METHYLENE CHLORIDE) CAS:75-09-2 RTECS #:PA8050000 Fraction by Wt: 98-100% OSHA PEL:500 PPM;1000 PPM, C ACGIH TLV:50 PPM EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS Ingred Name:SUPP DATA: NARCOSIS, WEAKNESS, DIZZ, FATG, GI IRRIT, NUMBNESS OF EXTREMITIES, CNS DEPRESS, & UNCON. CHRONIC: (ING 3) RTECS #:9999999ZZ Ingred Name:ING 2: EFTS OF OVEREXP MAY INCLUDE DAM TO KIDNEYS, LIVER, LUNGS, BLOOD, OR CENTRAL NERVOUS SYSTEM. TARGET ORGANS:(ING 4) RTECS #:9999999ZZ Ingred Name:ING 3: RESPIRATORY SYSTEM, LUNGS, CARDIOVASCULAR SYSTEM, CNS, LIVER, KIDNEYS, EYES, SKIN. RTECS #:9999999ZZ ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50: (ORAL, RAT) 2136 MG/KG. Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:YES IARC:YES OSHA:NO Health Hazards Acute and Chronic:CHLOROCARBON MATLS HAVE PRDCED SENSIT OF MYOCARDIUM TO EPINEPHRINE IN LAB ANIMALS & COULD HAVE A SIMILAR EFT IN HUMANS. ADRENOMIMETICS (E.G., EPINEPHRINE) MAY BE CONTRAINDICATED EXCEPT FOR LIFE-SUSTAI NING USES IN HUMANS ACUTELY/CHRONICALLYEXPOS TO CHLOROCARBONS . Explanation of Carcinogenicity:METHYLENE CHLORIDE: ANTICIP TO BE A CARCIN (NTP-6TH ANN RPT (SUM-1991), GRP 2B (IARC MNGRPH VOL SUP7, P194, 1987) Effects of Overexposure:INHAL & INGEST ARE HARMFUL & MAY BE FATAL.OVEREXP TO PROD CAN PRDCE ELEVATED CARBOXYHEMOGLOBIN LVLS IN BLOOD. INHAL OF VAPS MAY CAUSE HDCH, NAUS, VOMIT, NARCOSIS, WEAKNESS, FATG, DIZZ, IRRIT OF RESP T RACT, NUMBNESS OF EXTREMITIES, CNS DEPRESS, PULM EDEMA, & UNCON. CONT W/SKIN/EYES MAY CAUSE IRRIT. (SUPP DATA) Medical Cond Aggravated by Exposure:CARDIOVASCULAR DISORDERS, HEART DISORDERS, LIVER OR KIDNEY DISORDERS, CENTRAL NERVOUS SYSTEM DISORDERS, HEAVY DRINKERS, HEAVY SMOKERS. ======================= First Aid Measures ======================= First Aid:CALL A PHYSICIAN. INGEST: DO NOT INDUCE VOMIT. INHAL:MOVE TO FRESH AIR. IF NOT BRTHG GIVE ARTF RESP. IF BRTHG IS DFCLT, GIVE OXYGEN. EYE:IMMED FLUSH W/PLENTY OF WATER FOR AT LST 15 MIN. SKIN: IMMEDIAT ELY FLUSH WITH PLENTY OF WATER FOR AT LEAST 15 MINUTES WHILE REMOVING CONTAMINATED CLOTHING AND SHOES. NOTE TO MD: DO NOT USE ADRENALIN OR EPINEPHRINE. ===================== Fire Fighting Measures ===================== Lower Limits:12% Upper Limits:19% Extinguishing Media:USE EXTINGUISHING MEDIA APPROPRIATE FOR SURROUNDING FIRE. Fire Fighting Procedures:WEAR NIOSH/MSHA APPRVD PRESS DEMAND SCBA & FULL PROT EQUIP .MOVE CNTNRS FROM FIRE AREA IF IT CAN BE DONE W/OUT RISK.USE WATER TO KEEP (SUPP DATA) Unusual Fire/Explosion Hazard:TOX GASES PRDCED:HYDROGEN CHLORIDE, PHOSGENE, CHLORINE, CARBON MONOXIDE/DIOXIDE. CONCENTRATED VAP CAN BE IGNITED BY HIGH INTENSITY IGNIT SOURCE. VAP(SUPP DATA) ================== Accidental Release Measures ================== Spill Release Procedures:WEAR NIOSH/MSHA APPROVED SCBA & FULL PROT CLTHG. STOP LEAK IF YOU CAN DO SO W/OUT RISK. USE WATER SPRAY TO REDUCE VAPS. TAKE UP W/SAND/OTHER NON-COMBUST ABSORBENT MATL AND PLACE INTO CONTAINER FOR LAT ER DISPOSAL. FLUSH SPILL AREA WITH WATER. Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER. ====================== Handling and Storage ====================== Handling and Storage Precautions:KEEP CNTNR TIGHTLY CLSD.STORE IN SECURE POISON AREA.KEEP CNTNRS OUT OF SUN & AWAY FROM HEAT, MOISTURE. MATL IS HYGROSCOPIC. USE W/ADEQ VENTILATION. Other Precautions:NO SMOKING IN AREA OF USE.DO NOT USE IN GEN VICIN OF ARC WELDING, OPEN FLAMES/HOT SURFS.HEAT &/UV RADIATION MAY CAUSE FORMATION OF HCL &/PHOSGENE . AVOID CONT W/EYES, SKIN, CLOTHING. DO NOT BRTH E VAP.EXCEPTIONAL CONT HAZ - READ MSDS. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:NIOSH/MSHA APPROVED RESPIRATORY PROTECTION REQUIRED IF AIRBORNE CONCENTRATION EXCEEDS TLV. AT CONCENTRATIONS ABOVE 100 PPM, A NIOSH/MSHA APPROVED SCBA IS ADVISED. Ventilation:USE GENERAL OR LOCAL EXHAUST VENTILATION TO MEET TLV REQUIREMENTS. Protective Gloves:POLYVINYL ALCOHOL GLOVES. Eye Protection:CHEM WORK GOG & FULL LGTH FSHLD . Other Protective Equipment:UNIFORM, PROTECTIVE SUIT. EMERGENCY EYEWASH AND DELUGE SHOWER . Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING. EXERCISE DUE CARE. STORE AWAY FROM FOOD STUFFS. Supplemental Safety and Health FIRE FIGHT PROC: FIRE-EXPOS CNTNRS COOL. EXPLO HAZ: MAY FORM FLAMM MIX IN ATM THAT CONTAINS HIGH % OF OXYGEN. CLSD CNTNRS EXPOS TO HEAT MAY EXPLODE. EFTS OF OVEREXP:PRLNGD SKIN CONT MAY RSLT IN DERM. EYE CONT MAY RSLT IN TEMP CORNEAL DAM. SKIN ABSORPTION MAY BE HARMFUL. INGEST MAY CAUSE HDCH, NAUS, VOMIT, (ING 2) ================== Physical/Chemical Properties ================== Boiling Pt:B.P. Text:104F,40C Melt/Freeze Pt:M.P/F.P Text:-139F,-95C Vapor Pres:350 Vapor Density:2.9 Spec Gravity:1.32 (H*2O=1) Evaporation Rate & Reference:27.5 (BUTYL ACETATE=1) Solubility in Water:MODERATE (1-10%) Appearance and Odor:CLEAR, COLORLESS LIQUID; PENETRATING ETHER-LIKE ODOR. Percent Volatiles by Volume:100 ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALKALI METALS, STRONG OXIDIZING AGENTS, STRONG BASES, OXIDES OF NITROGEN, ZINC, ALUMINUM, WATER, MAGNESIUM,(SUPP DATA) Stability Condition to Avoid:HEAT, FLAME, OTHER SOURCES OF IGNITION, MOISTURE, LIGHT. Hazardous Decomposition Products:HYDROGEN CHLORIDE, PHOSGENE, CHLORINE, CARBON MONOXIDE, CARBON DIOXIDE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISPOSE I/A/W ALL APPLICABLE FEDERAL, STATE, AND LOCAL ENVIRONMENTAL REGULATIONS. EPA WASTE NUMBER U080. 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